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21.
Bahareh Heidari Majid M. Heravi Mohammad Reza Nabid Roya Sedghi Seyyed Emad Hooshmand 《应用有机金属化学》2019,33(1)
A novel nanocatalyst was designed and prepared. Initially, the surface of magnetic graphene oxide (M‐GO) was modified using thionyl chloride, tris(hydroxymethyl)aminomethane and acryloyl chloride as linkers which provide reactive C═C bonds for the polymerization of vinylic monomers. Separately, β‐cyclodextrin (β‐CD) was treated with acryloyl chloride to provide a modified β‐CD. Then, in the presence methylenebisacrylamide as a cross‐linker, monomers of modified β‐CD and acrylamide were polymerized on the surface of the pre‐prepared M‐GO. Finally, palladium acetate and sodium borohydride were added to this composite to afford supported palladium nanoparticles. This fabricated nanocomposite was fully characterized using various techniques. The efficiency of this easily separable and reusable heterogeneous catalyst was successfully examined in Suzuki–Miyaura cross‐coupling reactions of aryl halides and boronic acid as well as in modified Suzuki–Miyaura cross‐coupling reactions of N‐acylsuccinimides and boronic acid in green media. The results showed that the nanocatalyst was efficient in coupling reactions for direct formation of the corresponding biphenyl as well as benzophenone derivatives in green media based on bio‐based solvents. In addition, the nanocatalyst was easily separable, using an external magnet, and could be reused several times without significant loss of activity under the optimum reaction conditions. 相似文献
22.
Dr. Lorena García-Hevia Dr. Manuel Bañobre-López Dr. Juan Gallo 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(2):431-441
Manganese-based nanostructured contrast agents (CAs) entered the field of medical diagnosis through magnetic resonance imaging (MRI) some years ago. Although some of these Mn-based CAs behave as classic T1 contrast enhancers in the same way as clinical Gd-based molecules do, a new type of Mn nanomaterials have been developed to improve MRI sensitivity and potentially gather new functional information from tissues by using traditional T1 contrast enhanced MRI. These nanomaterials have been designed to respond to biological environments, mainly to pH and redox potential variations. In many cases, the differences in signal generation in these responsive Mn-based nanostructures come from intrinsic changes in the magnetic properties of Mn cations depending on their oxidation state. In other cases, no changes in the nature of Mn take place, but rather the nanomaterial as a whole responds to the change in the environment through different mechanisms, including changes in integrity and hydration state. This review focusses on the chemistry and MR performance of these responsive Mn-based nanomaterials. 相似文献
23.
In this study, core‐shell structures of magnetite nanoparticles coated with CMK‐8 ordered mesoporous carbon (Fe3O4@SiO2‐CMK‐8 NPs) have been successfully synthesized for the first time by carbonizing sucrose inside the pores of the Kit‐6 mesoporous silica. The nano‐sized mesoporous particles were characterized by X‐ray diffraction, Fourier transform‐infrared spectroscopy, scanning electron microscope, dynamic light scattering, vibrating‐sample magnetometer, Brunauer–Emmett–Teller (BET) and transmission electron microscopy instruments. The obtained nanocomposite was used for removal of Reactive Yellow 160 (RY 160) dye from aqueous samples. The N2 adsorption–desorption method (at 77 K) confirmed the mesoporous structure of synthesized Fe3O4@SiO2‐CMK‐8 NPs. Also, the surface area was calculated by the BET method and Langmuir plot as 276.84 m2/g and 352.32 m2/g, respectively. The surface area, volume and pore diameter of synthesized nanoparticles (NPs) were calculated from the pore size distribution curves using the Barrett–Joyner–Halenda formula (BJH). To obtain the optimum experimental variables, the effect of various experimental parameters on the dye removal efficiency was studied using Taguchi orthogonal array experimental design method. According to the experimental results, about 90.0% of RY 160 was removed from aqueous solutions at the adsorbent amount of 0.06 g, pH 3 and ionic strength = 0.05 m during 10 min. The pseudo‐second order kinetic model provided a very good fit for the RY 160 dye removal (R2 = 0.999). The Langmuir, Freundlich, Temkin and Dubinin–Radushkevich models were applied to describe the equilibrium isotherms, and the Langmuir isotherm showed the best fit to data with the maximum adsorption capacity of 62.893 mg/g. Furthermore, the Fe3O4@SiO2‐CMK‐8 NPs could be simply recovered by external magnet, and exhibited recyclability and reusability for a subsequent six runs. 相似文献
24.
Maryam Sohaniyan Mahboobeh Manoochehri Maryam Daghighi Asli 《Journal of separation science》2019,42(23):3528-3534
An efficient and fast dispersive magnetic solid phase extraction method was developed using MIL‐101(Cr)/poly (mercaptobenzothiazole)@magnetite nanoparticles for the preconcentration and determination of nitrophenols in river and rain water samples. High‐performance liquid chromatography‐Ultraviolet instrument was applied for the analysis of target nitrophenols. The effect of several variables on the extraction performance was explored via design of experiment approach. Limits of detection and linear dynamic ranges were attained in the range of 0.05–0.10 µg/L and 0.2–250 µg/L, respectively. The enrichment factors were in the range of 317–363. The precision (n = 3) of dispersive magnetic solid phase extraction method was in the range of 5.3–6.8%. Eventually, the method was utilized for the analysis of target nitrophenols in river and rain water samples. 相似文献
25.
基于单粒子导心运动代码ORBIT,采用测试粒子模拟方法,研究了托卡马克等离子体内部不同径向位置处局域磁场扰动对高能量离子的损失的影响。研究表明,在局域磁扰动主要分布在某磁面附近、其环向具有类似纹波场形式下,可造成一些靠近等离子体中心区域的高能量离子损失,但对靠近等离子边界的离子损失影响相对不大。这些损失的高能量离子均为捕获离子,离子的投掷角越大就越容易损失。此外,造成高能量离子最大损失率的局域场径向位置与这些损失离子的初始径向位置通常存在一定的偏移,而且这个偏移与这些离子的能量密切相关。当局域场出现在某些位置时,能量较低的离子会有一定的损失,能量较高的离子反而不会损失。 相似文献
26.
S. Sidi Ahmed G. Dimitri Ngantso M. Boujnah A. Benyoussef A. El Kenz 《Physics letters. A》2019,383(2-3):121-126
By using the density functional theory (DFT) and Monte Carlo simulations (MCS) with the Heisenberg model, we have studied magnetic properties of the bulk perovskite YCrO3. The exchange couplings of the Heisenberg model and the magnetic anisotropy are investigated. The 110 direction in the crystalline structure of the compound has shown the minimum energy, it is the easy magnetic direction. Using Monte Carlo simulations, the magnetizations behavior, the effects of system parameters and the critical exponents of the compound YCrO3 are implemented. It is shown that the bulk perovskite YCrO3 belongs to the 3D Heisenberg universality class. 相似文献
27.
28.
泛素(ubiquitin,Ub)是一种广泛存在、高度保守的信号蛋白质,它能够特异性识别成千上万种靶蛋白,以非共价方式行使不同的功能,其中包含蛋白质降解.Ubiquilin-1(Ubql-1)和Rad23A作为两种蛋白降解的转运因子,都包含有与泛素结合的结构域,被称为泛素结合域(ubiquitin-associated domain,UBA).2014年,泛素S65位磷酸化修饰的特异性激酶PINK1被发现,磷酸化使泛素在溶液中呈现舒展态与收缩态两种互相转换的构象.本文通过核磁共振(nuclear magnetic resonance,NMR)技术对UBA和磷酸化泛素之间的相互作用进行检测,观测磷酸化对UBA和泛素结合的影响.实验结果表明Rad23A-UBA2与Ubql-1 UBA都特异性的与磷酸化泛素的舒展态相互作用,但是磷酸化未改变泛素与UBA之间的亲和力.值得注意的是与Ubql-1 UBA相互作用时,磷酸化促进了泛素收缩态向舒展态的转换. 相似文献
29.
高强度聚焦超声(HIFU)是一种无创的热消融疗法,为保证其安全性和有效性,需要一种精度高、速度快的测温方法在其治疗过程中对温度进行监控.基于质子共振频率位移(PRFS)的磁共振温度成像(MRT)对温度具有较高的灵敏度,且与温度具有良好的线性关系,因此常被用于引导HIFU治疗.然而在实际应用中,HIFU治疗的最大隐患在于可能造成表皮灼伤,并且灼伤区域可能与焦点区域相隔较远.因此MRT的监控范围十分重要.本文基于三维回波平移成像序列,结合可控混叠的空间并行成像技术,实现了时间分辨率为3 s的快速三维温度成像.为了验证该方法的精度,本文首先设计了仿体降温实验,利用光纤温度计验证回波平移序列测温的准确度和精确度.然后在室温条件下扫描离体猪肉组织,对比加速前后的MRT的测温精确度.在HIFU加热条件下扫描离体猪肉组织,对比加速前后的MRT的测温准确度.结果显示,本文提出的方法可以在3 s内完成三维温度精准测量,对于HIFU治疗的安全监控具有重要意义. 相似文献
30.
Chunlai Wu Chuanyun Peng 《International journal of environmental analytical chemistry》2019,99(7):670-682
To develop an accurate and precise method for separation and pre-concentration of Hg(II), a novel thionin functionalised core shell structure magnetic material has been prepared and characterised. The extraction ability of the material was evaluated by magnetic solid-phase extraction coupled with inductively coupled plasma mass spectrometry determination of Hg(II) in food and water samples. Combining the advantages of magnetic separation with selective extraction of thionin towards Hg(II), the material exhibits enhanced enrich selectivity and efficiency for Hg(II). The experimental parameters influencing Hg(II) extraction efficiency, including pH of the aqueous solution, the dosage of the adsorbent, extraction time and sample volume, were systematically investigated. Under the optimised conditions, concentration of Hg(II) at 1.0 μg L?1 can be successfully enriched by the material without the interference of the common co-existing ions. The enrichment factor and adsorption capacity were 250 and 75.2 mg g?1, and precise of the method was confirmed by analysing the spiked food, water samples and standard water reference samples with the recoveries of 92.5–101.8%. 相似文献